The use of a well-defined surface organometallic complex as a probe molecule: $[(=SiO)Ta^{V}Cl_{2}Me_{2}]$ shows different isolated silanol sites on the silica surface

Yin Chen; Bin Zheng; Edy Abou-Hamad; Ali Imad Ali Hamieh; Bilel Hamzaoui; Kuo-Wei Huang; Jean-Marie Basset

doi:10.1039/c4cc04277h

The use of a well-defined surface organometallic complex as a probe molecule: $[(=SiO)Ta^{V}Cl_{2}Me_{2}]$ shows different isolated silanol sites on the silica surface

Yin Chen, Bin Zheng, Edy Abou-Hamad, Ali Imad Ali Hamieh, Bilel Hamzaoui, Kuo-Wei Huang, Jean-Marie Basset

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

TaVCl2Me3 reacts with silica(700) and produces two different [(≡SiO)TaVCl2Me2] surface organometallic species, suggesting a heterogeneity of the highly dehydroxylated silica surface, which was studied with a combined experimental and theoretical approach. This journal is © the Partner Organisations 2014.

Original language	English (US)
Pages (from-to)	11721-11723
Number of pages	3
Journal	Chem. Commun.
Volume	50
Issue number	79
DOIs	https://doi.org/10.1039/c4cc04277h
State	Published - 2014

ASJC Scopus subject areas

Materials Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Ceramics and Composites
General Chemistry
Catalysis
Electronic, Optical and Magnetic Materials

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10.1039/c4cc04277h

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title = "The use of a well-defined surface organometallic complex as a probe molecule: $[(=SiO)Ta^{V}Cl_{2}Me_{2}]$ shows different isolated silanol sites on the silica surface",

abstract = "TaVCl2Me3 reacts with silica(700) and produces two different [(≡SiO)TaVCl2Me2] surface organometallic species, suggesting a heterogeneity of the highly dehydroxylated silica surface, which was studied with a combined experimental and theoretical approach. This journal is {\textcopyright} the Partner Organisations 2014.",

author = "Yin Chen and Bin Zheng and Edy Abou-Hamad and Hamieh, {Ali Imad Ali} and Bilel Hamzaoui and Kuo-Wei Huang and Jean-Marie Basset",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We acknowledge the generous financial support from KAUST.",

year = "2014",

doi = "10.1039/c4cc04277h",

language = "English (US)",

volume = "50",

pages = "11721--11723",

journal = "Chem. Commun.",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - The use of a well-defined surface organometallic complex as a probe molecule: $[(=SiO)Ta^{V}Cl_{2}Me_{2}]$ shows different isolated silanol sites on the silica surface

AU - Chen, Yin

AU - Zheng, Bin

AU - Abou-Hamad, Edy

AU - Hamieh, Ali Imad Ali

AU - Hamzaoui, Bilel

AU - Huang, Kuo-Wei

AU - Basset, Jean-Marie

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We acknowledge the generous financial support from KAUST.

PY - 2014

Y1 - 2014

N2 - TaVCl2Me3 reacts with silica(700) and produces two different [(≡SiO)TaVCl2Me2] surface organometallic species, suggesting a heterogeneity of the highly dehydroxylated silica surface, which was studied with a combined experimental and theoretical approach. This journal is © the Partner Organisations 2014.

AB - TaVCl2Me3 reacts with silica(700) and produces two different [(≡SiO)TaVCl2Me2] surface organometallic species, suggesting a heterogeneity of the highly dehydroxylated silica surface, which was studied with a combined experimental and theoretical approach. This journal is © the Partner Organisations 2014.

UR - http://hdl.handle.net/10754/563275

UR - http://xlink.rsc.org/?DOI=C4CC04277H

UR - http://www.scopus.com/inward/record.url?scp=84929224026&partnerID=8YFLogxK

U2 - 10.1039/c4cc04277h

DO - 10.1039/c4cc04277h

M3 - Article

C2 - 25142307

SN - 1359-7345

VL - 50

SP - 11721

EP - 11723

JO - Chem. Commun.

JF - Chem. Commun.

IS - 79

ER -

The use of a well-defined surface organometallic complex as a probe molecule: $[(=SiO)Ta^{V}Cl_{2}Me_{2}]$ shows different isolated silanol sites on the silica surface

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ASJC Scopus subject areas

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