Thermal decomposition products of the heteronuclear complex, LaNi(dhbaen) (NO3)(H2O)n

Hiromichi Aono; Nobuyuki Kondo; Masatomi Sakamoto; Enrico Traversa; Yoshihiko Sadaoka

doi:10.1016/S0955-2219(02)00350-3

Thermal decomposition products of the heteronuclear complex, LaNi(dhbaen) (NO₃)(H₂O)n

Hiromichi Aono, Nobuyuki Kondo, Masatomi Sakamoto, Enrico Traversa, Yoshihiko Sadaoka^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The heteronuclear LaNi(dhbaen)(NO₃ )(H₂ O) _n complex was synthesized and its thermal decomposition products were analyzed by differential thermal analysis (TG/DTA), X-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectroscopy, Auger electron spectroscopy (AES) with scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Hexagonal perovskite-type LaNiO₃ having fine particle size was obtained by sintering at 600°C. AES showed that the elemental distributions of La, Ni, and O on the surface were very homogeneous for the sample decomposed at 900°C. The LaNiO₃ decomposed to La₃ Ni₂ O₇ and NiO when the heating temperature increases up to 1000°C. Heteronuclear LnNi(dhbaen)(NO₃ )(H₂ O)n complexes (with Ln=Pr, Nd, Sm, and Gd) were also synthesized. The perovskite-type LnNiO₃ phase could not be formed by their thermal decomposition.

Original language	English (US)
Pages (from-to)	1375-1381
Number of pages	7
Journal	Journal of the European Ceramic Society
Volume	23
Issue number	9
DOIs	https://doi.org/10.1016/S0955-2219(02)00350-3
State	Published - Aug 2003
Externally published	Yes

Keywords

Calcination
LaNiO
Organic
Phase development
Precursors

ASJC Scopus subject areas

Ceramics and Composites
Materials Chemistry

Access to Document

10.1016/S0955-2219(02)00350-3

Cite this

@article{85a4d8fec10e4a2f8df435fab67c1568,

title = "Thermal decomposition products of the heteronuclear complex, LaNi(dhbaen) (NO3)(H2O)n",

abstract = "The heteronuclear LaNi(dhbaen)(NO3 )(H2 O) n complex was synthesized and its thermal decomposition products were analyzed by differential thermal analysis (TG/DTA), X-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectroscopy, Auger electron spectroscopy (AES) with scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Hexagonal perovskite-type LaNiO3 having fine particle size was obtained by sintering at 600°C. AES showed that the elemental distributions of La, Ni, and O on the surface were very homogeneous for the sample decomposed at 900°C. The LaNiO3 decomposed to La3 Ni2 O7 and NiO when the heating temperature increases up to 1000°C. Heteronuclear LnNi(dhbaen)(NO3 )(H2 O)n complexes (with Ln=Pr, Nd, Sm, and Gd) were also synthesized. The perovskite-type LnNiO3 phase could not be formed by their thermal decomposition.",

keywords = "Calcination, LaNiO, Organic, Phase development, Precursors",

author = "Hiromichi Aono and Nobuyuki Kondo and Masatomi Sakamoto and Enrico Traversa and Yoshihiko Sadaoka",

year = "2003",

month = aug,

doi = "10.1016/S0955-2219(02)00350-3",

language = "English (US)",

volume = "23",

pages = "1375--1381",

journal = "Journal of the European Ceramic Society",

issn = "0955-2219",

publisher = "Elsevier",

number = "9",

}

TY - JOUR

T1 - Thermal decomposition products of the heteronuclear complex, LaNi(dhbaen) (NO3)(H2O)n

AU - Aono, Hiromichi

AU - Kondo, Nobuyuki

AU - Sakamoto, Masatomi

AU - Traversa, Enrico

AU - Sadaoka, Yoshihiko

PY - 2003/8

Y1 - 2003/8

N2 - The heteronuclear LaNi(dhbaen)(NO3 )(H2 O) n complex was synthesized and its thermal decomposition products were analyzed by differential thermal analysis (TG/DTA), X-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectroscopy, Auger electron spectroscopy (AES) with scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Hexagonal perovskite-type LaNiO3 having fine particle size was obtained by sintering at 600°C. AES showed that the elemental distributions of La, Ni, and O on the surface were very homogeneous for the sample decomposed at 900°C. The LaNiO3 decomposed to La3 Ni2 O7 and NiO when the heating temperature increases up to 1000°C. Heteronuclear LnNi(dhbaen)(NO3 )(H2 O)n complexes (with Ln=Pr, Nd, Sm, and Gd) were also synthesized. The perovskite-type LnNiO3 phase could not be formed by their thermal decomposition.

AB - The heteronuclear LaNi(dhbaen)(NO3 )(H2 O) n complex was synthesized and its thermal decomposition products were analyzed by differential thermal analysis (TG/DTA), X-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectroscopy, Auger electron spectroscopy (AES) with scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Hexagonal perovskite-type LaNiO3 having fine particle size was obtained by sintering at 600°C. AES showed that the elemental distributions of La, Ni, and O on the surface were very homogeneous for the sample decomposed at 900°C. The LaNiO3 decomposed to La3 Ni2 O7 and NiO when the heating temperature increases up to 1000°C. Heteronuclear LnNi(dhbaen)(NO3 )(H2 O)n complexes (with Ln=Pr, Nd, Sm, and Gd) were also synthesized. The perovskite-type LnNiO3 phase could not be formed by their thermal decomposition.

KW - Calcination

KW - LaNiO

KW - Organic

KW - Phase development

KW - Precursors

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DO - 10.1016/S0955-2219(02)00350-3

M3 - Article

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SN - 0955-2219

VL - 23

SP - 1375

EP - 1381

JO - Journal of the European Ceramic Society

JF - Journal of the European Ceramic Society

IS - 9

ER -