Titanium coordination compounds: from discrete metal complexes to metal–organic frameworks

Hala Assi; Georges Mouchaham; Nathalie Steunou; Thomas Devic; Christian Serre

doi:10.1039/c7cs00001d

Titanium coordination compounds: from discrete metal complexes to metal–organic frameworks

Hala Assi, Georges Mouchaham, Nathalie Steunou, Thomas Devic, Christian Serre

Physical Sciences and Engineering

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252 Scopus citations

Abstract

Owing to their promise in photocatalysis and optoelectronics, titanium based metal–organic frameworks (MOFs) are one of the most appealing classes of MOFs reported to date. Nevertheless, Ti-MOFs are still very scarce because of their challenging synthesis associated with a poor degree of control of their chemistry and crystallization. This review aims at giving an overview of the recent progress in this field focusing on the most relevant existing titanium coordination compounds as well as their promising photoredox properties. Not only Ti-MOFs but also Ti-oxo-clusters will be discussed and particular interest will be dedicated to highlight the different successful synthetic strategies allowing to overcome the still “unpredictable” reactivity of titanium ions, particularly to afford crystalline porous coordination polymers.

Original language	English (US)
Pages (from-to)	3431-3431
Number of pages	1
Journal	Chem. Soc. Rev.
Volume	46
Issue number	11
DOIs	https://doi.org/10.1039/c7cs00001d
State	Published - May 24 2017

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title = "Titanium coordination compounds: from discrete metal complexes to metal–organic frameworks",

abstract = "Owing to their promise in photocatalysis and optoelectronics, titanium based metal–organic frameworks (MOFs) are one of the most appealing classes of MOFs reported to date. Nevertheless, Ti-MOFs are still very scarce because of their challenging synthesis associated with a poor degree of control of their chemistry and crystallization. This review aims at giving an overview of the recent progress in this field focusing on the most relevant existing titanium coordination compounds as well as their promising photoredox properties. Not only Ti-MOFs but also Ti-oxo-clusters will be discussed and particular interest will be dedicated to highlight the different successful synthetic strategies allowing to overcome the still “unpredictable” reactivity of titanium ions, particularly to afford crystalline porous coordination polymers.",

author = "Hala Assi and Georges Mouchaham and Nathalie Steunou and Thomas Devic and Christian Serre",

note = "KAUST Repository Item: Exported on 2018-05-17 Acknowledgements: The authors acknowledge past and present coworkers involved in the synthesis and characterization of new MOFs, especially those involved in the chemistry of Ti-MOFs (H. Dan-Hardi, V. Guillerm, N. Guillou, P. Horcajada, T. L. A. Nguyen, F. Nouar, L. C. Pardo-Perez, F. Ragon and G. F{\'e}rey).",

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doi = "10.1039/c7cs00001d",

language = "English (US)",

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pages = "3431--3431",

journal = "Chem. Soc. Rev.",

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T1 - Titanium coordination compounds: from discrete metal complexes to metal–organic frameworks

AU - Assi, Hala

AU - Mouchaham, Georges

AU - Steunou, Nathalie

AU - Devic, Thomas

AU - Serre, Christian

N1 - KAUST Repository Item: Exported on 2018-05-17 Acknowledgements: The authors acknowledge past and present coworkers involved in the synthesis and characterization of new MOFs, especially those involved in the chemistry of Ti-MOFs (H. Dan-Hardi, V. Guillerm, N. Guillou, P. Horcajada, T. L. A. Nguyen, F. Nouar, L. C. Pardo-Perez, F. Ragon and G. Férey).

PY - 2017/5/24

Y1 - 2017/5/24

N2 - Owing to their promise in photocatalysis and optoelectronics, titanium based metal–organic frameworks (MOFs) are one of the most appealing classes of MOFs reported to date. Nevertheless, Ti-MOFs are still very scarce because of their challenging synthesis associated with a poor degree of control of their chemistry and crystallization. This review aims at giving an overview of the recent progress in this field focusing on the most relevant existing titanium coordination compounds as well as their promising photoredox properties. Not only Ti-MOFs but also Ti-oxo-clusters will be discussed and particular interest will be dedicated to highlight the different successful synthetic strategies allowing to overcome the still “unpredictable” reactivity of titanium ions, particularly to afford crystalline porous coordination polymers.

AB - Owing to their promise in photocatalysis and optoelectronics, titanium based metal–organic frameworks (MOFs) are one of the most appealing classes of MOFs reported to date. Nevertheless, Ti-MOFs are still very scarce because of their challenging synthesis associated with a poor degree of control of their chemistry and crystallization. This review aims at giving an overview of the recent progress in this field focusing on the most relevant existing titanium coordination compounds as well as their promising photoredox properties. Not only Ti-MOFs but also Ti-oxo-clusters will be discussed and particular interest will be dedicated to highlight the different successful synthetic strategies allowing to overcome the still “unpredictable” reactivity of titanium ions, particularly to afford crystalline porous coordination polymers.

UR - http://hdl.handle.net/10754/625114

UR - http://pubs.rsc.org/en/Content/ArticleLanding/2017/CS/C7CS00001D#!divAbstract

U2 - 10.1039/c7cs00001d

DO - 10.1039/c7cs00001d

M3 - Article

C2 - 28537319

SN - 0306-0012

VL - 46

SP - 3431

EP - 3431

JO - Chem. Soc. Rev.

JF - Chem. Soc. Rev.

IS - 11

ER -

Titanium coordination compounds: from discrete metal complexes to metal–organic frameworks

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