TY - JOUR
T1 - Transformation of Nickelalactones to Methyl Acrylate: On the Way to a Catalytic Conversion of Carbon Dioxide
AU - Lee, S. Y. Tina
AU - Cokoja, Mirza
AU - Drees, Markus
AU - Li, Yang
AU - Mink, János
AU - Herrmann, Wolfgang A.
AU - Kühn, Fritz E.
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): KSA-C0069/UK-C0020
Acknowledgements: This publication is based on work supported by Award KSA-C0069/UK-C0020, made by the King Abdullah University of Science and Technology (KAUST). The authors thank Dr. Bettina Bechlars for the measurement and refinement of the X-ray single crystal structure of complex 1. The authors also thank the Leibniz-Rechenzentrum for providing computing time.
This publication acknowledges KAUST support, but has no KAUST affiliated authors.
PY - 2011/8/26
Y1 - 2011/8/26
N2 - Mu-nick: The methyl iodide-mediated ring opening of nickelalactones, which can be formed by oxidative coupling of carbon dioxide and ethylene at Ni 0 complexes, induces β-H elimination, producing methyl acrylate in yields of up to 56 %. This reaction is found to be very sensitive to the ligands coordinated to the central nickel atom. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
AB - Mu-nick: The methyl iodide-mediated ring opening of nickelalactones, which can be formed by oxidative coupling of carbon dioxide and ethylene at Ni 0 complexes, induces β-H elimination, producing methyl acrylate in yields of up to 56 %. This reaction is found to be very sensitive to the ligands coordinated to the central nickel atom. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
UR - http://hdl.handle.net/10754/600060
UR - http://doi.wiley.com/10.1002/cssc.201000445
UR - http://www.scopus.com/inward/record.url?scp=80052929060&partnerID=8YFLogxK
U2 - 10.1002/cssc.201000445
DO - 10.1002/cssc.201000445
M3 - Article
C2 - 21922679
SN - 1864-5631
VL - 4
SP - 1275
EP - 1279
JO - ChemSusChem
JF - ChemSusChem
IS - 9
ER -