TY - JOUR
T1 - Triphenylphosphine-Based Covalent Organic Frameworks and Heterogeneous Rh-P-COFs Catalysts.
AU - Liu, Yubing
AU - Dikhtiarenko, Alla
AU - Xu, Naizhang
AU - Sun, Jiawei
AU - Tang, Jie
AU - Wang, Kaiqiang
AU - Xu, Bolian
AU - Tong, Qing
AU - Heeres, Hero Jan
AU - He, Songbo
AU - Gascon, Jorge
AU - Fan, Yining
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: Y. Liu and Y. Fan thank National Natural Science Foundation of China (NSFC), S. He and H.J. Heeres thank Netherlands Organization for Scientific Research (NWO) for their financial support (NSFC Grant No. 21773107 and NWO-LIFT Programme Grant No.731.016.401) to this work.
PY - 2020/6/4
Y1 - 2020/6/4
N2 - The synthesis of phosphine-based functional covalent organic frameworks (COFs) has attracted great attention recently. Here, we present two examples of triphenylphosphine-based COFs (termed as P-COFs) with well-defined crystalline structures, high specific surface areas and good thermal stability. Furthermore, the rhodium catalysts using the obtained P-COFs as support materials show high turnover frequency (TOF) for the hydroformylation of olefins, as well as the excellent recycling performance. This work not only extended phosphine-based COFs family, but also demonstrated their application in immobilizing homogeneous metal-based (e.g., Rh-phosphine) catalysts for heterogeneous catalysis application.
AB - The synthesis of phosphine-based functional covalent organic frameworks (COFs) has attracted great attention recently. Here, we present two examples of triphenylphosphine-based COFs (termed as P-COFs) with well-defined crystalline structures, high specific surface areas and good thermal stability. Furthermore, the rhodium catalysts using the obtained P-COFs as support materials show high turnover frequency (TOF) for the hydroformylation of olefins, as well as the excellent recycling performance. This work not only extended phosphine-based COFs family, but also demonstrated their application in immobilizing homogeneous metal-based (e.g., Rh-phosphine) catalysts for heterogeneous catalysis application.
UR - http://hdl.handle.net/10754/663252
UR - https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202002150
U2 - 10.1002/chem.202002150
DO - 10.1002/chem.202002150
M3 - Article
C2 - 32488940
SN - 0947-6539
JO - Chemistry (Weinheim an der Bergstrasse, Germany)
JF - Chemistry (Weinheim an der Bergstrasse, Germany)
ER -