Tuning physicochemical properties of hierarchically ZSM-5/FDU-12 composite material and its catalytic hydrodesulfurization performance for diesel

Jiyuan Fan; Honglei Zhang; Chengkun Xiao; Jinlin Mei; Yu Shi; Aijun Duan; Guiyuan Jiang

doi:10.1016/j.cattod.2020.12.035

Tuning physicochemical properties of hierarchically ZSM-5/FDU-12 composite material and its catalytic hydrodesulfurization performance for diesel

Jiyuan Fan, Honglei Zhang, Chengkun Xiao, Jinlin Mei, Yu Shi, Aijun Duan, Guiyuan Jiang

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A series of ZSM-5/FDU-12 (ZF-x) composite material with MFI microporous structure and face-centered cubic structure were successfully synthesized using the nano-assembly method under different water bath temperatures. The bath temperature had an apparent influence on the material's physical texture property. The catalytic hydrotreating performance were evaluated inside fix-bed unit, under the reaction conditions of 5 MPa and 350 °C. The sulfur and nitrogen contents of the products obtained from NiMo/ZFA-30 catalyst were reached 11.5 ppm and 4.8 ppm, respectively. The moderate acidity and the highest sulfidation ratio of active phases were responsible for the highest hydrodesulfurization (98.9 %) and hydrodenitrogenation (99.3 %) efficiency over the NiMo/ZFA-30 catalyst.

Original language	English (US)
Pages (from-to)	162-172
Number of pages	11
Journal	Catalysis Today
Volume	374
DOIs	https://doi.org/10.1016/j.cattod.2020.12.035
State	Published - Jun 10 2021
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
Catalysis

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10.1016/j.cattod.2020.12.035

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@article{ee78914214fb48acb435ba2b45a31915,

title = "Tuning physicochemical properties of hierarchically ZSM-5/FDU-12 composite material and its catalytic hydrodesulfurization performance for diesel",

abstract = "A series of ZSM-5/FDU-12 (ZF-x) composite material with MFI microporous structure and face-centered cubic structure were successfully synthesized using the nano-assembly method under different water bath temperatures. The bath temperature had an apparent influence on the material's physical texture property. The catalytic hydrotreating performance were evaluated inside fix-bed unit, under the reaction conditions of 5 MPa and 350 °C. The sulfur and nitrogen contents of the products obtained from NiMo/ZFA-30 catalyst were reached 11.5 ppm and 4.8 ppm, respectively. The moderate acidity and the highest sulfidation ratio of active phases were responsible for the highest hydrodesulfurization (98.9 %) and hydrodenitrogenation (99.3 %) efficiency over the NiMo/ZFA-30 catalyst.",

author = "Jiyuan Fan and Honglei Zhang and Chengkun Xiao and Jinlin Mei and Yu Shi and Aijun Duan and Guiyuan Jiang",

note = "KAUST Repository Item: Exported on 2022-06-14 Acknowledged KAUST grant number(s): OSR-2019-CPF-4103.2 Acknowledgements: This work was financially supported by the National Natural Science Foundation of China (No. 21878330, 21676298), the National Science and Technology Major Project, CNPC Key Research Project (2016E-0707) and the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) under Award (No. OSR-2019-CPF-4103.2). This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

year = "2021",

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doi = "10.1016/j.cattod.2020.12.035",

language = "English (US)",

volume = "374",

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T1 - Tuning physicochemical properties of hierarchically ZSM-5/FDU-12 composite material and its catalytic hydrodesulfurization performance for diesel

AU - Fan, Jiyuan

AU - Zhang, Honglei

AU - Xiao, Chengkun

AU - Mei, Jinlin

AU - Shi, Yu

AU - Duan, Aijun

AU - Jiang, Guiyuan

N1 - KAUST Repository Item: Exported on 2022-06-14 Acknowledged KAUST grant number(s): OSR-2019-CPF-4103.2 Acknowledgements: This work was financially supported by the National Natural Science Foundation of China (No. 21878330, 21676298), the National Science and Technology Major Project, CNPC Key Research Project (2016E-0707) and the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) under Award (No. OSR-2019-CPF-4103.2). This publication acknowledges KAUST support, but has no KAUST affiliated authors.

PY - 2021/6/10

Y1 - 2021/6/10

N2 - A series of ZSM-5/FDU-12 (ZF-x) composite material with MFI microporous structure and face-centered cubic structure were successfully synthesized using the nano-assembly method under different water bath temperatures. The bath temperature had an apparent influence on the material's physical texture property. The catalytic hydrotreating performance were evaluated inside fix-bed unit, under the reaction conditions of 5 MPa and 350 °C. The sulfur and nitrogen contents of the products obtained from NiMo/ZFA-30 catalyst were reached 11.5 ppm and 4.8 ppm, respectively. The moderate acidity and the highest sulfidation ratio of active phases were responsible for the highest hydrodesulfurization (98.9 %) and hydrodenitrogenation (99.3 %) efficiency over the NiMo/ZFA-30 catalyst.

AB - A series of ZSM-5/FDU-12 (ZF-x) composite material with MFI microporous structure and face-centered cubic structure were successfully synthesized using the nano-assembly method under different water bath temperatures. The bath temperature had an apparent influence on the material's physical texture property. The catalytic hydrotreating performance were evaluated inside fix-bed unit, under the reaction conditions of 5 MPa and 350 °C. The sulfur and nitrogen contents of the products obtained from NiMo/ZFA-30 catalyst were reached 11.5 ppm and 4.8 ppm, respectively. The moderate acidity and the highest sulfidation ratio of active phases were responsible for the highest hydrodesulfurization (98.9 %) and hydrodenitrogenation (99.3 %) efficiency over the NiMo/ZFA-30 catalyst.

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DO - 10.1016/j.cattod.2020.12.035

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JO - Catalysis Today

JF - Catalysis Today

ER -

Tuning physicochemical properties of hierarchically ZSM-5/FDU-12 composite material and its catalytic hydrodesulfurization performance for diesel

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