Two-dimensional charge-transfer molecular design: control of anisotropy in linear and nonlinear optical properties for photonic device applications

Takashi Isoshima; Tatsuo Wada; Ya Dong Zhang; Tetsuya Aoyama; Jean Luc Bredas; Hiroyuki Sasabe

Two-dimensional charge-transfer molecular design: control of anisotropy in linear and nonlinear optical properties for photonic device applications

Takashi Isoshima^*, Tatsuo Wada, Ya Dong Zhang, Tetsuya Aoyama, Jean Luc Bredas, Hiroyuki Sasabe

^*Corresponding author for this work

Research output: Contribution to journal › Conference article › peer-review

3 Scopus citations

Abstract

The advantage of two-dimensional (2-D) charge-transfer (CT) chromophore in a poled polymeric system over 1-D CT ones is theoretically demonstrated in terms of photonic device applications. Poling behavior of second harmonic generation coefficient and linear polarizability tensor components are calculated for carbazole derivatives with 2-D and 1-D CT character. It is shown that, in a 2-D CT compound, the off-diagonal components present 1.5 times as large value as those in a 1-D CT compounds. In addition, the 2-D CT compound presents less anisotropy in refractive index than the 1-D CT compound, and thus smaller change in it with orientation relaxation.

Original language	English (US)
Pages (from-to)	65-68
Number of pages	4
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics
Volume	15
Issue number	1-4
State	Published - 1996
Externally published	Yes
Event	Proceedings of the 1995 2nd International Conference on Organic Nonlinear Optics, ICONO'2 - Kusatsu, Jpn Duration: Jul 23 1995 → Jul 26 1995

ASJC Scopus subject areas

Control and Systems Engineering
Condensed Matter Physics

Cite this

@article{0d584ed28e7044e2aa864e0af89db70d,

title = "Two-dimensional charge-transfer molecular design: control of anisotropy in linear and nonlinear optical properties for photonic device applications",

abstract = "The advantage of two-dimensional (2-D) charge-transfer (CT) chromophore in a poled polymeric system over 1-D CT ones is theoretically demonstrated in terms of photonic device applications. Poling behavior of second harmonic generation coefficient and linear polarizability tensor components are calculated for carbazole derivatives with 2-D and 1-D CT character. It is shown that, in a 2-D CT compound, the off-diagonal components present 1.5 times as large value as those in a 1-D CT compounds. In addition, the 2-D CT compound presents less anisotropy in refractive index than the 1-D CT compound, and thus smaller change in it with orientation relaxation.",

author = "Takashi Isoshima and Tatsuo Wada and Zhang, {Ya Dong} and Tetsuya Aoyama and Bredas, {Jean Luc} and Hiroyuki Sasabe",

year = "1996",

language = "English (US)",

volume = "15",

pages = "65--68",

journal = "Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics",

issn = "1058-7268",

publisher = "Old City Publishing",

number = "1-4",

note = "Proceedings of the 1995 2nd International Conference on Organic Nonlinear Optics, ICONO'2 ; Conference date: 23-07-1995 Through 26-07-1995",

}

Two-dimensional charge-transfer molecular design: control of anisotropy in linear and nonlinear optical properties for photonic device applications. / Isoshima, Takashi; Wada, Tatsuo; Zhang, Ya Dong et al.
In: Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics, Vol. 15, No. 1-4, 1996, p. 65-68.

Research output: Contribution to journal › Conference article › peer-review

TY - JOUR

T1 - Two-dimensional charge-transfer molecular design

T2 - Proceedings of the 1995 2nd International Conference on Organic Nonlinear Optics, ICONO'2

AU - Isoshima, Takashi

AU - Wada, Tatsuo

AU - Zhang, Ya Dong

AU - Aoyama, Tetsuya

AU - Bredas, Jean Luc

AU - Sasabe, Hiroyuki

PY - 1996

Y1 - 1996

N2 - The advantage of two-dimensional (2-D) charge-transfer (CT) chromophore in a poled polymeric system over 1-D CT ones is theoretically demonstrated in terms of photonic device applications. Poling behavior of second harmonic generation coefficient and linear polarizability tensor components are calculated for carbazole derivatives with 2-D and 1-D CT character. It is shown that, in a 2-D CT compound, the off-diagonal components present 1.5 times as large value as those in a 1-D CT compounds. In addition, the 2-D CT compound presents less anisotropy in refractive index than the 1-D CT compound, and thus smaller change in it with orientation relaxation.

AB - The advantage of two-dimensional (2-D) charge-transfer (CT) chromophore in a poled polymeric system over 1-D CT ones is theoretically demonstrated in terms of photonic device applications. Poling behavior of second harmonic generation coefficient and linear polarizability tensor components are calculated for carbazole derivatives with 2-D and 1-D CT character. It is shown that, in a 2-D CT compound, the off-diagonal components present 1.5 times as large value as those in a 1-D CT compounds. In addition, the 2-D CT compound presents less anisotropy in refractive index than the 1-D CT compound, and thus smaller change in it with orientation relaxation.

UR - http://www.scopus.com/inward/record.url?scp=0029771343&partnerID=8YFLogxK

M3 - Conference article

AN - SCOPUS:0029771343

SN - 1058-7268

VL - 15

SP - 65

EP - 68

JO - Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics

JF - Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics

IS - 1-4

Y2 - 23 July 1995 through 26 July 1995

ER -

Two-dimensional charge-transfer molecular design: control of anisotropy in linear and nonlinear optical properties for photonic device applications

Abstract

ASJC Scopus subject areas

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