Two-dimensional sandwich-type, graphene-based conjugated microporous polymers

Xiaodong Zhuang; Fan Zhang; Dongqing Wu; Nina Forler; Haiwei Liang; Manfred Wagner; Dominik Gehrig; Michael Ryan Hansen; Frédéric Laquai; Xinliang Feng

doi:10.1002/anie.201304496

Two-dimensional sandwich-type, graphene-based conjugated microporous polymers

Xiaodong Zhuang, Fan Zhang^*, Dongqing Wu, Nina Forler, Haiwei Liang, Manfred Wagner, Dominik Gehrig, Michael Ryan Hansen, Frédéric Laquai, Xinliang Feng

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

215 Scopus citations

Abstract

Better than sliced bread: Layered two-dimensional graphene-based conjugated microporous polymers, which exhibit high surface areas and fluorescence quenching, can be prepared by a graphene-mediated Sonogashira-Hagihara coupling. Upon thermal pyrolysis, these porous polymers are readily converted into porous carbon materials with intriguing physical and electrochemical properties (see scheme; pink spheres=thiophene, thiazole, or pyridine units).

Original language	English (US)
Pages (from-to)	9668-9672
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	37
DOIs	https://doi.org/10.1002/anie.201304496
State	Published - Sep 9 2013
Externally published	Yes

Keywords

conjugated microporous polymers
donor-acceptor systems
graphene
oxygen reduction reaction
porous carbon

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.201304496

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title = "Two-dimensional sandwich-type, graphene-based conjugated microporous polymers",

abstract = "Better than sliced bread: Layered two-dimensional graphene-based conjugated microporous polymers, which exhibit high surface areas and fluorescence quenching, can be prepared by a graphene-mediated Sonogashira-Hagihara coupling. Upon thermal pyrolysis, these porous polymers are readily converted into porous carbon materials with intriguing physical and electrochemical properties (see scheme; pink spheres=thiophene, thiazole, or pyridine units).",

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doi = "10.1002/anie.201304496",

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AU - Zhuang, Xiaodong

AU - Zhang, Fan

AU - Wu, Dongqing

AU - Forler, Nina

AU - Liang, Haiwei

AU - Wagner, Manfred

AU - Gehrig, Dominik

AU - Hansen, Michael Ryan

AU - Laquai, Frédéric

AU - Feng, Xinliang

PY - 2013/9/9

Y1 - 2013/9/9

N2 - Better than sliced bread: Layered two-dimensional graphene-based conjugated microporous polymers, which exhibit high surface areas and fluorescence quenching, can be prepared by a graphene-mediated Sonogashira-Hagihara coupling. Upon thermal pyrolysis, these porous polymers are readily converted into porous carbon materials with intriguing physical and electrochemical properties (see scheme; pink spheres=thiophene, thiazole, or pyridine units).

AB - Better than sliced bread: Layered two-dimensional graphene-based conjugated microporous polymers, which exhibit high surface areas and fluorescence quenching, can be prepared by a graphene-mediated Sonogashira-Hagihara coupling. Upon thermal pyrolysis, these porous polymers are readily converted into porous carbon materials with intriguing physical and electrochemical properties (see scheme; pink spheres=thiophene, thiazole, or pyridine units).

KW - conjugated microporous polymers

KW - donor-acceptor systems

KW - graphene

KW - oxygen reduction reaction

KW - porous carbon

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DO - 10.1002/anie.201304496

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 37

ER -

Two-dimensional sandwich-type, graphene-based conjugated microporous polymers

Abstract

Keywords

ASJC Scopus subject areas

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