Two enantiomorphic 3D Zn(ii)-carboxylate MOFs with double helical structures serving as a chiral source induced by hydrogen bonding

Huabin Zhang; Shuting Wu; Chongbin Tian; Zujin Lin; Zhihua Li; Ping Lin; Shaowu Du

doi:10.1039/c2ce25325a

Two enantiomorphic 3D Zn(ii)-carboxylate MOFs with double helical structures serving as a chiral source induced by hydrogen bonding

Huabin Zhang, Shuting Wu, Chongbin Tian, Zujin Lin, Zhihua Li, Ping Lin, Shaowu Du

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Two enantiomorphic 3D Zn(ii)-carboxylate metal-organic frameworks [Zn(bpydc)(H2O)2] (1M and 1P) (H2bpydc = 2,2′-bipyridyl-5,5′-dicarboxylic acid) have been synthesized. They both contain an elegant double helix, self-organized through hydrogen bonds between the coordinated water molecules and uncoordinated carboxylate oxygen atoms. This double helical structure serves as a chiral source which transmits chiral information over the whole 3D framework. © 2012 The Royal Society of Chemistry.

Original language	English (US)
Pages (from-to)	4165-4167
Number of pages	3
Journal	CrystEngComm
Volume	14
Issue number	12
DOIs	https://doi.org/10.1039/c2ce25325a
State	Published - Jun 21 2012
Externally published	Yes

ASJC Scopus subject areas

General Materials Science
General Chemistry
Condensed Matter Physics

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abstract = "Two enantiomorphic 3D Zn(ii)-carboxylate metal-organic frameworks [Zn(bpydc)(H2O)2] (1M and 1P) (H2bpydc = 2,2′-bipyridyl-5,5′-dicarboxylic acid) have been synthesized. They both contain an elegant double helix, self-organized through hydrogen bonds between the coordinated water molecules and uncoordinated carboxylate oxygen atoms. This double helical structure serves as a chiral source which transmits chiral information over the whole 3D framework. {\textcopyright} 2012 The Royal Society of Chemistry.",

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T1 - Two enantiomorphic 3D Zn(ii)-carboxylate MOFs with double helical structures serving as a chiral source induced by hydrogen bonding

AU - Zhang, Huabin

AU - Wu, Shuting

AU - Tian, Chongbin

AU - Lin, Zujin

AU - Li, Zhihua

AU - Lin, Ping

AU - Du, Shaowu

N1 - Generated from Scopus record by KAUST IRTS on 2022-09-15

PY - 2012/6/21

Y1 - 2012/6/21

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AB - Two enantiomorphic 3D Zn(ii)-carboxylate metal-organic frameworks [Zn(bpydc)(H2O)2] (1M and 1P) (H2bpydc = 2,2′-bipyridyl-5,5′-dicarboxylic acid) have been synthesized. They both contain an elegant double helix, self-organized through hydrogen bonds between the coordinated water molecules and uncoordinated carboxylate oxygen atoms. This double helical structure serves as a chiral source which transmits chiral information over the whole 3D framework. © 2012 The Royal Society of Chemistry.

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Two enantiomorphic 3D Zn(ii)-carboxylate MOFs with double helical structures serving as a chiral source induced by hydrogen bonding

Abstract

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