Two-photon absorption at telecommunications wavelengths in a dipolar chromophore with a pyrrole auxiliary donor and thiazole auxiliary acceptor

Luca Beverina; Jie Fu; Amalia Leclercq; Egbert Zojer; Peter Pacher; Stephen Barlow; Eric W. Van Stryland; David J. Hagan; Jean Luc Brédas; Seth R. Marder

doi:10.1021/ja050688l

Two-photon absorption at telecommunications wavelengths in a dipolar chromophore with a pyrrole auxiliary donor and thiazole auxiliary acceptor

Luca Beverina, Jie Fu, Amalia Leclercq, Egbert Zojer, Peter Pacher, Stephen Barlow, Eric W. Van Stryland, David J. Hagan, Jean Luc Brédas, Seth R. Marder^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

161 Scopus citations

Abstract

Three new dipolar chromophores based on a diaklyaminophenyl donor, a pyrrole auxiliary donor, a thiazole auxiliary acceptor, and strong heterocyclic acceptors have been synthesized. For one of these compounds we have measured a very large non-degenerate two-photon cross section of ca. 1500 GM in the near-IR telecommunications range using a pump-probe technique. Calculations indicate the cross section for degenerate two-photon absorption is likely to be ca. 60% of this value.

Original language	English (US)
Pages (from-to)	7282-7283
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	127
Issue number	20
DOIs	https://doi.org/10.1021/ja050688l
State	Published - May 25 2005
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
Biochemistry
Catalysis
Colloid and Surface Chemistry

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Beverina, L., Fu, J., Leclercq, A., Zojer, E., Pacher, P., Barlow, S., Van Stryland, E. W., Hagan, D. J., Brédas, J. L., & Marder, S. R. (2005). Two-photon absorption at telecommunications wavelengths in a dipolar chromophore with a pyrrole auxiliary donor and thiazole auxiliary acceptor. Journal of the American Chemical Society, 127(20), 7282-7283. https://doi.org/10.1021/ja050688l

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abstract = "Three new dipolar chromophores based on a diaklyaminophenyl donor, a pyrrole auxiliary donor, a thiazole auxiliary acceptor, and strong heterocyclic acceptors have been synthesized. For one of these compounds we have measured a very large non-degenerate two-photon cross section of ca. 1500 GM in the near-IR telecommunications range using a pump-probe technique. Calculations indicate the cross section for degenerate two-photon absorption is likely to be ca. 60% of this value.",

author = "Luca Beverina and Jie Fu and Amalia Leclercq and Egbert Zojer and Peter Pacher and Stephen Barlow and {Van Stryland}, {Eric W.} and Hagan, {David J.} and Br{\'e}das, {Jean Luc} and Marder, {Seth R.}",

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doi = "10.1021/ja050688l",

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Beverina, L, Fu, J, Leclercq, A, Zojer, E, Pacher, P, Barlow, S, Van Stryland, EW, Hagan, DJ, Brédas, JL & Marder, SR 2005, 'Two-photon absorption at telecommunications wavelengths in a dipolar chromophore with a pyrrole auxiliary donor and thiazole auxiliary acceptor', Journal of the American Chemical Society, vol. 127, no. 20, pp. 7282-7283. https://doi.org/10.1021/ja050688l

TY - JOUR

T1 - Two-photon absorption at telecommunications wavelengths in a dipolar chromophore with a pyrrole auxiliary donor and thiazole auxiliary acceptor

AU - Beverina, Luca

AU - Fu, Jie

AU - Leclercq, Amalia

AU - Zojer, Egbert

AU - Pacher, Peter

AU - Barlow, Stephen

AU - Van Stryland, Eric W.

AU - Hagan, David J.

AU - Brédas, Jean Luc

AU - Marder, Seth R.

PY - 2005/5/25

Y1 - 2005/5/25

N2 - Three new dipolar chromophores based on a diaklyaminophenyl donor, a pyrrole auxiliary donor, a thiazole auxiliary acceptor, and strong heterocyclic acceptors have been synthesized. For one of these compounds we have measured a very large non-degenerate two-photon cross section of ca. 1500 GM in the near-IR telecommunications range using a pump-probe technique. Calculations indicate the cross section for degenerate two-photon absorption is likely to be ca. 60% of this value.

AB - Three new dipolar chromophores based on a diaklyaminophenyl donor, a pyrrole auxiliary donor, a thiazole auxiliary acceptor, and strong heterocyclic acceptors have been synthesized. For one of these compounds we have measured a very large non-degenerate two-photon cross section of ca. 1500 GM in the near-IR telecommunications range using a pump-probe technique. Calculations indicate the cross section for degenerate two-photon absorption is likely to be ca. 60% of this value.

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U2 - 10.1021/ja050688l

DO - 10.1021/ja050688l

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 20

ER -

Two-photon absorption at telecommunications wavelengths in a dipolar chromophore with a pyrrole auxiliary donor and thiazole auxiliary acceptor

Abstract

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