Two-photon absorption in quadrupolar bis(acceptor)-terminated chromophores with electron-rich bis(heterocycle)vinylene bridges

Shijun Zheng; Amalia Leclercq; Jie Fu; Luca Beverina; Lazaro A. Padilha; Egbert Zojer; Karin Schmidt; Stephen Barlow; Jingdong Luo; Sei Hum Jiang; Alex K.Y. Jen; Yuanping Yi; Zhigang Shuai; Eric W. Van Stryland; David J. Hagan; Jean Luc Brédas; Seth R. Marder

doi:10.1021/cm061681l

Two-photon absorption in quadrupolar bis(acceptor)-terminated chromophores with electron-rich bis(heterocycle)vinylene bridges

Shijun Zheng, Amalia Leclercq, Jie Fu, Luca Beverina, Lazaro A. Padilha, Egbert Zojer, Karin Schmidt, Stephen Barlow, Jingdong Luo, Sei Hum Jiang, Alex K.Y. Jen, Yuanping Yi, Zhigang Shuai, Eric W. Van Stryland, David J. Hagan, Jean Luc Brédas, Seth R. Marder^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

71 Scopus citations

Abstract

Two-photon absorption spectra for a range of bis(acceptor)-substituted bis(dibutoxythienyl)ethene and bis(N-hexylpyrrolyl)ethene chromophores have been recorded using Z-scan and white-light-continuum pump-probe techniques. All the chromophores studied show strong near-infrared two-photon absorption with cross sections in the range of 2400-5900 GM (1 GM = 1 × 10^-50 cm ⁴ s/photon) at photon wavelengths between 1.0 and 1.3 μm; cross sections as high as 10000 GM can be accessed close to the one-photon absorption edge. Quantum-chemical calculations reproduce the experimentally observed variations of the two-photon properties with the chemical structure.

Original language	English (US)
Pages (from-to)	432-442
Number of pages	11
Journal	Chemistry of Materials
Volume	19
Issue number	3
DOIs	https://doi.org/10.1021/cm061681l
State	Published - Feb 6 2007
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Materials Chemistry

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10.1021/cm061681l

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Zheng, S., Leclercq, A., Fu, J., Beverina, L., Padilha, L. A., Zojer, E., Schmidt, K., Barlow, S., Luo, J., Jiang, S. H., Jen, A. K. Y., Yi, Y., Shuai, Z., Van Stryland, E. W., Hagan, D. J., Brédas, J. L., & Marder, S. R. (2007). Two-photon absorption in quadrupolar bis(acceptor)-terminated chromophores with electron-rich bis(heterocycle)vinylene bridges. Chemistry of Materials, 19(3), 432-442. https://doi.org/10.1021/cm061681l

@article{af9fdd46e0f34f13945203f8dd1ee1e7,

title = "Two-photon absorption in quadrupolar bis(acceptor)-terminated chromophores with electron-rich bis(heterocycle)vinylene bridges",

abstract = "Two-photon absorption spectra for a range of bis(acceptor)-substituted bis(dibutoxythienyl)ethene and bis(N-hexylpyrrolyl)ethene chromophores have been recorded using Z-scan and white-light-continuum pump-probe techniques. All the chromophores studied show strong near-infrared two-photon absorption with cross sections in the range of 2400-5900 GM (1 GM = 1 × 10-50 cm 4 s/photon) at photon wavelengths between 1.0 and 1.3 μm; cross sections as high as 10000 GM can be accessed close to the one-photon absorption edge. Quantum-chemical calculations reproduce the experimentally observed variations of the two-photon properties with the chemical structure.",

author = "Shijun Zheng and Amalia Leclercq and Jie Fu and Luca Beverina and Padilha, {Lazaro A.} and Egbert Zojer and Karin Schmidt and Stephen Barlow and Jingdong Luo and Jiang, {Sei Hum} and Jen, {Alex K.Y.} and Yuanping Yi and Zhigang Shuai and {Van Stryland}, {Eric W.} and Hagan, {David J.} and Br{\'e}das, {Jean Luc} and Marder, {Seth R.}",

year = "2007",

month = feb,

day = "6",

doi = "10.1021/cm061681l",

language = "English (US)",

volume = "19",

pages = "432--442",

journal = "Chemistry of Materials",

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Zheng, S, Leclercq, A, Fu, J, Beverina, L, Padilha, LA, Zojer, E, Schmidt, K, Barlow, S, Luo, J, Jiang, SH, Jen, AKY, Yi, Y, Shuai, Z, Van Stryland, EW, Hagan, DJ, Brédas, JL & Marder, SR 2007, 'Two-photon absorption in quadrupolar bis(acceptor)-terminated chromophores with electron-rich bis(heterocycle)vinylene bridges', Chemistry of Materials, vol. 19, no. 3, pp. 432-442. https://doi.org/10.1021/cm061681l

TY - JOUR

T1 - Two-photon absorption in quadrupolar bis(acceptor)-terminated chromophores with electron-rich bis(heterocycle)vinylene bridges

AU - Zheng, Shijun

AU - Leclercq, Amalia

AU - Fu, Jie

AU - Beverina, Luca

AU - Padilha, Lazaro A.

AU - Zojer, Egbert

AU - Schmidt, Karin

AU - Barlow, Stephen

AU - Luo, Jingdong

AU - Jiang, Sei Hum

AU - Jen, Alex K.Y.

AU - Yi, Yuanping

AU - Shuai, Zhigang

AU - Van Stryland, Eric W.

AU - Hagan, David J.

AU - Brédas, Jean Luc

AU - Marder, Seth R.

PY - 2007/2/6

Y1 - 2007/2/6

N2 - Two-photon absorption spectra for a range of bis(acceptor)-substituted bis(dibutoxythienyl)ethene and bis(N-hexylpyrrolyl)ethene chromophores have been recorded using Z-scan and white-light-continuum pump-probe techniques. All the chromophores studied show strong near-infrared two-photon absorption with cross sections in the range of 2400-5900 GM (1 GM = 1 × 10-50 cm 4 s/photon) at photon wavelengths between 1.0 and 1.3 μm; cross sections as high as 10000 GM can be accessed close to the one-photon absorption edge. Quantum-chemical calculations reproduce the experimentally observed variations of the two-photon properties with the chemical structure.

AB - Two-photon absorption spectra for a range of bis(acceptor)-substituted bis(dibutoxythienyl)ethene and bis(N-hexylpyrrolyl)ethene chromophores have been recorded using Z-scan and white-light-continuum pump-probe techniques. All the chromophores studied show strong near-infrared two-photon absorption with cross sections in the range of 2400-5900 GM (1 GM = 1 × 10-50 cm 4 s/photon) at photon wavelengths between 1.0 and 1.3 μm; cross sections as high as 10000 GM can be accessed close to the one-photon absorption edge. Quantum-chemical calculations reproduce the experimentally observed variations of the two-photon properties with the chemical structure.

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U2 - 10.1021/cm061681l

DO - 10.1021/cm061681l

M3 - Article

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SN - 0897-4756

VL - 19

SP - 432

EP - 442

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 3

ER -

Two-photon absorption in quadrupolar bis(acceptor)-terminated chromophores with electron-rich bis(heterocycle)vinylene bridges

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