Unusual [CdII3O2(CO2) 8] clusters as SBUs for the construction of a new pcu-type metal-organic framework

Yan Fei Chen; Hua Bin Zhang; Shu Mei Chen

doi:10.1016/j.inoche.2013.09.024

Unusual [CdII3O2(CO2) 8] clusters as SBUs for the construction of a new pcu-type metal-organic framework

Yan Fei Chen, Hua Bin Zhang, Shu Mei Chen

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A novel 3D metal-organic framework (Me2NH2) 2[Cd3(H2-DHBDC)3(CH 3COO)2(DMF)2](DMF)2 (H 4-DHBDC = 2,5-dihydroxy-1,4-benzenedicarboxylic acid) with unusual [CdII3O2(CO2)8] building blocks has been solvothermally synthesized. It features a typical pcu topology by reducing the [CdII3O2(CO2) 8] building blocks as the 6-connected nodes. The physical properties such as thermogravimetric analyses (TGA), IR, elemental analysis, powder X-ray diffraction (PXRD) and photoluminescence were investigated in detail. © 2013 Elsevier B.V.

Original language	English (US)
Pages (from-to)	11-13
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	38
DOIs	https://doi.org/10.1016/j.inoche.2013.09.024
State	Published - Oct 30 2013
Externally published	Yes

ASJC Scopus subject areas

Materials Chemistry
Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1016/j.inoche.2013.09.024

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title = "Unusual [CdII3O2(CO2) 8] clusters as SBUs for the construction of a new pcu-type metal-organic framework",

abstract = "A novel 3D metal-organic framework (Me2NH2) 2[Cd3(H2-DHBDC)3(CH 3COO)2(DMF)2](DMF)2 (H 4-DHBDC = 2,5-dihydroxy-1,4-benzenedicarboxylic acid) with unusual [CdII3O2(CO2)8] building blocks has been solvothermally synthesized. It features a typical pcu topology by reducing the [CdII3O2(CO2) 8] building blocks as the 6-connected nodes. The physical properties such as thermogravimetric analyses (TGA), IR, elemental analysis, powder X-ray diffraction (PXRD) and photoluminescence were investigated in detail. {\textcopyright} 2013 Elsevier B.V.",

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AU - Chen, Yan Fei

AU - Zhang, Hua Bin

AU - Chen, Shu Mei

N1 - Generated from Scopus record by KAUST IRTS on 2022-09-15

PY - 2013/10/30

Y1 - 2013/10/30

N2 - A novel 3D metal-organic framework (Me2NH2) 2[Cd3(H2-DHBDC)3(CH 3COO)2(DMF)2](DMF)2 (H 4-DHBDC = 2,5-dihydroxy-1,4-benzenedicarboxylic acid) with unusual [CdII3O2(CO2)8] building blocks has been solvothermally synthesized. It features a typical pcu topology by reducing the [CdII3O2(CO2) 8] building blocks as the 6-connected nodes. The physical properties such as thermogravimetric analyses (TGA), IR, elemental analysis, powder X-ray diffraction (PXRD) and photoluminescence were investigated in detail. © 2013 Elsevier B.V.

AB - A novel 3D metal-organic framework (Me2NH2) 2[Cd3(H2-DHBDC)3(CH 3COO)2(DMF)2](DMF)2 (H 4-DHBDC = 2,5-dihydroxy-1,4-benzenedicarboxylic acid) with unusual [CdII3O2(CO2)8] building blocks has been solvothermally synthesized. It features a typical pcu topology by reducing the [CdII3O2(CO2) 8] building blocks as the 6-connected nodes. The physical properties such as thermogravimetric analyses (TGA), IR, elemental analysis, powder X-ray diffraction (PXRD) and photoluminescence were investigated in detail. © 2013 Elsevier B.V.

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JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Unusual [CdII3O2(CO2) 8] clusters as SBUs for the construction of a new pcu-type metal-organic framework

Abstract

ASJC Scopus subject areas

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