Unusual stereoselectivities in olefin metathesis

Michel Leconte; J. L. Bilhou; W. Reimann; J. M. Basset

doi:10.1039/C39780000341

Unusual stereoselectivities in olefin metathesis

Michel Leconte, J. L. Bilhou, W. Reimann, J. M. Basset^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The stereoselectivity of metathesis of various olefins (cis- or trans-RCH=CHMe) decreases with increasing bulk of the R groups; this corresponds to an increased randomness of the various modes of olefin co-ordination to the metallo-carbene intermediate.

Original language	English (US)
Pages (from-to)	341-342
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/C39780000341
State	Published - 1978
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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title = "Unusual stereoselectivities in olefin metathesis",

abstract = "The stereoselectivity of metathesis of various olefins (cis- or trans-RCH=CHMe) decreases with increasing bulk of the R groups; this corresponds to an increased randomness of the various modes of olefin co-ordination to the metallo-carbene intermediate.",

author = "Michel Leconte and Bilhou, {J. L.} and W. Reimann and Basset, {J. M.}",

year = "1978",

doi = "10.1039/C39780000341",

language = "English (US)",

pages = "341--342",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "8",

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T1 - Unusual stereoselectivities in olefin metathesis

AU - Leconte, Michel

AU - Bilhou, J. L.

AU - Reimann, W.

AU - Basset, J. M.

PY - 1978

Y1 - 1978

N2 - The stereoselectivity of metathesis of various olefins (cis- or trans-RCH=CHMe) decreases with increasing bulk of the R groups; this corresponds to an increased randomness of the various modes of olefin co-ordination to the metallo-carbene intermediate.

AB - The stereoselectivity of metathesis of various olefins (cis- or trans-RCH=CHMe) decreases with increasing bulk of the R groups; this corresponds to an increased randomness of the various modes of olefin co-ordination to the metallo-carbene intermediate.

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U2 - 10.1039/C39780000341

DO - 10.1039/C39780000341

M3 - Article

AN - SCOPUS:37049110484

SN - 0022-4936

SP - 341

EP - 342

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 8

ER -

Unusual stereoselectivities in olefin metathesis

Abstract

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