Update: An efficient synthesis of poly(ethylene glycol)-supported iron(II) porphyrin using a click reaction and its application for the catalytic olefination of aldehydes

Tamilselvi R. Chinnusamy; Valentin Rodionov; Fritz Kühn; Oliver Reiser

doi:10.1002/adsc.201100289

Update: An efficient synthesis of poly(ethylene glycol)-supported iron(II) porphyrin using a click reaction and its application for the catalytic olefination of aldehydes

Tamilselvi R. Chinnusamy, Valentin Rodionov, Fritz Kühn, Oliver Reiser

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

The facile synthesis of polyethylene glycol (PEG)-immobilized iron(II) porphyrin using a copper-catalyzed azide-alkyne [3+2] cycloaddition "click" reaction is reported. The prepared complex 5 (PEG-C 51H 39FeN 7O) was found to be an efficient catalyst for the selective olefination of aldehydes with ethyl diazoacetate in the presence of triphenylphosphine, and afforded excellent olefin yields with high (E) selectivities. The PEG-supported catalyst 5 was readily recovered by precipitation and filtration, and was recycled through ten runs without significant activity loss. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English (US)
Pages (from-to)	1827-1831
Number of pages	5
Journal	Advanced Synthesis & Catalysis
Volume	354
Issue number	9
DOIs	https://doi.org/10.1002/adsc.201100289
State	Published - May 9 2012

ASJC Scopus subject areas

Organic Chemistry
Catalysis

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10.1002/adsc.201100289

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title = "Update: An efficient synthesis of poly(ethylene glycol)-supported iron(II) porphyrin using a click reaction and its application for the catalytic olefination of aldehydes",

abstract = "The facile synthesis of polyethylene glycol (PEG)-immobilized iron(II) porphyrin using a copper-catalyzed azide-alkyne [3+2] cycloaddition {"}click{"} reaction is reported. The prepared complex 5 (PEG-C 51H 39FeN 7O) was found to be an efficient catalyst for the selective olefination of aldehydes with ethyl diazoacetate in the presence of triphenylphosphine, and afforded excellent olefin yields with high (E) selectivities. The PEG-supported catalyst 5 was readily recovered by precipitation and filtration, and was recycled through ten runs without significant activity loss. Copyright {\textcopyright} 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

author = "Chinnusamy, {Tamilselvi R.} and Valentin Rodionov and Fritz K{\"u}hn and Oliver Reiser",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by the Bavarian Elite Network NANOCAT.",

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Update: An efficient synthesis of poly(ethylene glycol)-supported iron(II) porphyrin using a click reaction and its application for the catalytic olefination of aldehydes. / Chinnusamy, Tamilselvi R.; Rodionov, Valentin; Kühn, Fritz et al.
In: Advanced Synthesis & Catalysis, Vol. 354, No. 9, 09.05.2012, p. 1827-1831.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Update: An efficient synthesis of poly(ethylene glycol)-supported iron(II) porphyrin using a click reaction and its application for the catalytic olefination of aldehydes

AU - Chinnusamy, Tamilselvi R.

AU - Rodionov, Valentin

AU - Kühn, Fritz

AU - Reiser, Oliver

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by the Bavarian Elite Network NANOCAT.

PY - 2012/5/9

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AB - The facile synthesis of polyethylene glycol (PEG)-immobilized iron(II) porphyrin using a copper-catalyzed azide-alkyne [3+2] cycloaddition "click" reaction is reported. The prepared complex 5 (PEG-C 51H 39FeN 7O) was found to be an efficient catalyst for the selective olefination of aldehydes with ethyl diazoacetate in the presence of triphenylphosphine, and afforded excellent olefin yields with high (E) selectivities. The PEG-supported catalyst 5 was readily recovered by precipitation and filtration, and was recycled through ten runs without significant activity loss. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Update: An efficient synthesis of poly(ethylene glycol)-supported iron(II) porphyrin using a click reaction and its application for the catalytic olefination of aldehydes

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