Upscale synthesis of a binary pillared layered MOF for hydrocarbon gas storage and separation

Mickaele Bonneau; Christophe Lavenn; Patrick Ginet; Ken Ichi Otake; Susumu Kitagawa

doi:10.1039/c9gc03561c

Upscale synthesis of a binary pillared layered MOF for hydrocarbon gas storage and separation

Mickaele Bonneau, Christophe Lavenn, Patrick Ginet, Ken Ichi Otake, Susumu Kitagawa^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

102 Scopus citations

Abstract

Scaling up the synthesis of metal organic frameworks (MOFs) is necessary in order to demonstrate their potential in industrial applications. This requires the development of a cost efficient and environmentally friendly synthesis protocol which necessitates the understanding of the reaction mechanism, especially for more complex binary ligand MOF systems. Herein, we demonstrate the upscale synthesis (≥100 g) of CPL-1[Cu₂(pzdc)₂(pz)]_n using water as the solvent. The MOF is a binary ligand system composed of 2D layers of copper (Cu(ii)) coordinated to 2,3-pyrazinedicarboxylate (pzdc^2-) connected by pyrazine pillars (pz). The reaction conditions were investigated and found to be optimal when using the minimum amount of reagent possible in water by adjusting the pH to 6.4 leading to CPL-1 formation with high yield (95% yields) and space-time yield (660 kg m^-3 day^-1). In addition, the upscaled MOF exhibited similar sorption and separation capacity to the lab scaled one.

Original language	English (US)
Pages (from-to)	718-724
Number of pages	7
Journal	Green Chemistry
Volume	22
Issue number	3
DOIs	https://doi.org/10.1039/c9gc03561c
State	Published - Feb 7 2020

ASJC Scopus subject areas

Environmental Chemistry
Pollution

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title = "Upscale synthesis of a binary pillared layered MOF for hydrocarbon gas storage and separation",

abstract = "Scaling up the synthesis of metal organic frameworks (MOFs) is necessary in order to demonstrate their potential in industrial applications. This requires the development of a cost efficient and environmentally friendly synthesis protocol which necessitates the understanding of the reaction mechanism, especially for more complex binary ligand MOF systems. Herein, we demonstrate the upscale synthesis (≥100 g) of CPL-1[Cu2(pzdc)2(pz)]n using water as the solvent. The MOF is a binary ligand system composed of 2D layers of copper (Cu(ii)) coordinated to 2,3-pyrazinedicarboxylate (pzdc2-) connected by pyrazine pillars (pz). The reaction conditions were investigated and found to be optimal when using the minimum amount of reagent possible in water by adjusting the pH to 6.4 leading to CPL-1 formation with high yield (95% yields) and space-time yield (660 kg m-3 day-1). In addition, the upscaled MOF exhibited similar sorption and separation capacity to the lab scaled one.",

author = "Mickaele Bonneau and Christophe Lavenn and Patrick Ginet and Otake, {Ken Ichi} and Susumu Kitagawa",

note = "Funding Information: This work was supported by funding from Air Liquide via the 2016 Air Liquide Scientific Challenge, a KAKENHI Grant-in-Aid for Specially Promoted Research (JP25000007), Scientific Research (S) (JP18H05262), and Early-Career Scientists (JP19K15584) from the Japan Society of the Promotion of Science (JSPS). Publisher Copyright: {\textcopyright} 2020 The Royal Society of Chemistry.",

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AU - Kitagawa, Susumu

N1 - Funding Information: This work was supported by funding from Air Liquide via the 2016 Air Liquide Scientific Challenge, a KAKENHI Grant-in-Aid for Specially Promoted Research (JP25000007), Scientific Research (S) (JP18H05262), and Early-Career Scientists (JP19K15584) from the Japan Society of the Promotion of Science (JSPS). Publisher Copyright: © 2020 The Royal Society of Chemistry.

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N2 - Scaling up the synthesis of metal organic frameworks (MOFs) is necessary in order to demonstrate their potential in industrial applications. This requires the development of a cost efficient and environmentally friendly synthesis protocol which necessitates the understanding of the reaction mechanism, especially for more complex binary ligand MOF systems. Herein, we demonstrate the upscale synthesis (≥100 g) of CPL-1[Cu2(pzdc)2(pz)]n using water as the solvent. The MOF is a binary ligand system composed of 2D layers of copper (Cu(ii)) coordinated to 2,3-pyrazinedicarboxylate (pzdc2-) connected by pyrazine pillars (pz). The reaction conditions were investigated and found to be optimal when using the minimum amount of reagent possible in water by adjusting the pH to 6.4 leading to CPL-1 formation with high yield (95% yields) and space-time yield (660 kg m-3 day-1). In addition, the upscaled MOF exhibited similar sorption and separation capacity to the lab scaled one.

AB - Scaling up the synthesis of metal organic frameworks (MOFs) is necessary in order to demonstrate their potential in industrial applications. This requires the development of a cost efficient and environmentally friendly synthesis protocol which necessitates the understanding of the reaction mechanism, especially for more complex binary ligand MOF systems. Herein, we demonstrate the upscale synthesis (≥100 g) of CPL-1[Cu2(pzdc)2(pz)]n using water as the solvent. The MOF is a binary ligand system composed of 2D layers of copper (Cu(ii)) coordinated to 2,3-pyrazinedicarboxylate (pzdc2-) connected by pyrazine pillars (pz). The reaction conditions were investigated and found to be optimal when using the minimum amount of reagent possible in water by adjusting the pH to 6.4 leading to CPL-1 formation with high yield (95% yields) and space-time yield (660 kg m-3 day-1). In addition, the upscaled MOF exhibited similar sorption and separation capacity to the lab scaled one.

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Upscale synthesis of a binary pillared layered MOF for hydrocarbon gas storage and separation

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