Using small building blocks to assemble ultra-complex, multifaceted metal-organic frameworks with zeolitic, mesoporous subnetwork

Jiantang Li; Dorina F. Sava; Vincent Guillerm; Taslim Melliti; Ryan Luebke; Jarrod F. Eubank; Prashant M. Bhatt; Hao Jiang; Mickaele Bonneau; Youssef Belmabkhout; Zhiyuan Huang; Aleksander Shkurenko; Lukasz Wojtas; Michael O'Keeffe; Mohamed Eddaoudi

doi:10.1016/j.chempr.2023.09.026

Using small building blocks to assemble ultra-complex, multifaceted metal-organic frameworks with zeolitic, mesoporous subnetwork

Jiantang Li, Dorina F. Sava, Vincent Guillerm, Taslim Melliti, Ryan Luebke, Jarrod F. Eubank, Prashant M. Bhatt, Hao Jiang, Mickaele Bonneau, Youssef Belmabkhout, Zhiyuan Huang, Aleksander Shkurenko, Lukasz Wojtas, Michael O'Keeffe, Mohamed Eddaoudi^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The assembly of ultra-complex structures from simple building units remains a long-term challenge in chemistry. Using small molecular building blocks (MBBs) in a mixed-ligand approach permitted the assembly of unprecedented metal-organic frameworks (MOFs), M-kum-MOF-1 (M = Y, Tb), exhibiting extra-large mesoporous cavities with small access windows. The ultra-complex cage of M-kum-MOF-1 consists of 240 vertices bridged by 432 edges, leading to a 194 faces-containing tile. This tile exhibits more faces than in any periodic structures (zeolites, MOFs, metal-organic polyhedra [MOPs], etc.) known to date. M-kum-MOF-1 not only possess zeolitic features (anionic framework), but they also contain an underlying wse zeolitic topology, which is observed for the first time.

Original language	English (US)
Pages (from-to)	567-577
Number of pages	11
Journal	Chem
Volume	10
Issue number	2
DOIs	https://doi.org/10.1016/j.chempr.2023.09.026
State	Accepted/In press - 2024

Keywords

metal-organic framework
molecular cage
polyhedra
reticular chemistry
SDG7: Affordable and clean energy
self-assembly
topology

ASJC Scopus subject areas

General Chemistry
Biochemistry
Environmental Chemistry
General Chemical Engineering
Biochemistry, medical
Materials Chemistry

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10.1016/j.chempr.2023.09.026

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Li, J., Sava, D. F., Guillerm, V., Melliti, T., Luebke, R., Eubank, J. F., Bhatt, P. M., Jiang, H., Bonneau, M., Belmabkhout, Y., Huang, Z., Shkurenko, A., Wojtas, L., O'Keeffe, M., & Eddaoudi, M. (Accepted/In press). Using small building blocks to assemble ultra-complex, multifaceted metal-organic frameworks with zeolitic, mesoporous subnetwork. Chem, 10(2), 567-577. https://doi.org/10.1016/j.chempr.2023.09.026

@article{e05c2a4f1f4d4e3d97b377b67fafa680,

title = "Using small building blocks to assemble ultra-complex, multifaceted metal-organic frameworks with zeolitic, mesoporous subnetwork",

abstract = "The assembly of ultra-complex structures from simple building units remains a long-term challenge in chemistry. Using small molecular building blocks (MBBs) in a mixed-ligand approach permitted the assembly of unprecedented metal-organic frameworks (MOFs), M-kum-MOF-1 (M = Y, Tb), exhibiting extra-large mesoporous cavities with small access windows. The ultra-complex cage of M-kum-MOF-1 consists of 240 vertices bridged by 432 edges, leading to a 194 faces-containing tile. This tile exhibits more faces than in any periodic structures (zeolites, MOFs, metal-organic polyhedra [MOPs], etc.) known to date. M-kum-MOF-1 not only possess zeolitic features (anionic framework), but they also contain an underlying wse zeolitic topology, which is observed for the first time.",

keywords = "metal-organic framework, molecular cage, polyhedra, reticular chemistry, SDG7: Affordable and clean energy, self-assembly, topology",

author = "Jiantang Li and Sava, {Dorina F.} and Vincent Guillerm and Taslim Melliti and Ryan Luebke and Eubank, {Jarrod F.} and Bhatt, {Prashant M.} and Hao Jiang and Mickaele Bonneau and Youssef Belmabkhout and Zhiyuan Huang and Aleksander Shkurenko and Lukasz Wojtas and Michael O'Keeffe and Mohamed Eddaoudi",

note = "Publisher Copyright: {\textcopyright} 2023",

year = "2024",

doi = "10.1016/j.chempr.2023.09.026",

language = "English (US)",

volume = "10",

pages = "567--577",

journal = "Chem",

issn = "2451-9308",

publisher = "Elsevier",

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Li, J, Sava, DF, Guillerm, V, Melliti, T, Luebke, R, Eubank, JF, Bhatt, PM, Jiang, H, Bonneau, M, Belmabkhout, Y, Huang, Z, Shkurenko, A, Wojtas, L, O'Keeffe, M & Eddaoudi, M 2024, 'Using small building blocks to assemble ultra-complex, multifaceted metal-organic frameworks with zeolitic, mesoporous subnetwork', Chem, vol. 10, no. 2, pp. 567-577. https://doi.org/10.1016/j.chempr.2023.09.026

TY - JOUR

T1 - Using small building blocks to assemble ultra-complex, multifaceted metal-organic frameworks with zeolitic, mesoporous subnetwork

AU - Li, Jiantang

AU - Sava, Dorina F.

AU - Guillerm, Vincent

AU - Melliti, Taslim

AU - Luebke, Ryan

AU - Eubank, Jarrod F.

AU - Bhatt, Prashant M.

AU - Jiang, Hao

AU - Bonneau, Mickaele

AU - Belmabkhout, Youssef

AU - Huang, Zhiyuan

AU - Shkurenko, Aleksander

AU - Wojtas, Lukasz

AU - O'Keeffe, Michael

AU - Eddaoudi, Mohamed

PY - 2024

Y1 - 2024

N2 - The assembly of ultra-complex structures from simple building units remains a long-term challenge in chemistry. Using small molecular building blocks (MBBs) in a mixed-ligand approach permitted the assembly of unprecedented metal-organic frameworks (MOFs), M-kum-MOF-1 (M = Y, Tb), exhibiting extra-large mesoporous cavities with small access windows. The ultra-complex cage of M-kum-MOF-1 consists of 240 vertices bridged by 432 edges, leading to a 194 faces-containing tile. This tile exhibits more faces than in any periodic structures (zeolites, MOFs, metal-organic polyhedra [MOPs], etc.) known to date. M-kum-MOF-1 not only possess zeolitic features (anionic framework), but they also contain an underlying wse zeolitic topology, which is observed for the first time.

AB - The assembly of ultra-complex structures from simple building units remains a long-term challenge in chemistry. Using small molecular building blocks (MBBs) in a mixed-ligand approach permitted the assembly of unprecedented metal-organic frameworks (MOFs), M-kum-MOF-1 (M = Y, Tb), exhibiting extra-large mesoporous cavities with small access windows. The ultra-complex cage of M-kum-MOF-1 consists of 240 vertices bridged by 432 edges, leading to a 194 faces-containing tile. This tile exhibits more faces than in any periodic structures (zeolites, MOFs, metal-organic polyhedra [MOPs], etc.) known to date. M-kum-MOF-1 not only possess zeolitic features (anionic framework), but they also contain an underlying wse zeolitic topology, which is observed for the first time.

KW - metal-organic framework

KW - molecular cage

KW - polyhedra

KW - reticular chemistry

KW - SDG7: Affordable and clean energy

KW - self-assembly

KW - topology

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U2 - 10.1016/j.chempr.2023.09.026

DO - 10.1016/j.chempr.2023.09.026

M3 - Article

AN - SCOPUS:85182356169

SN - 2451-9308

VL - 10

SP - 567

EP - 577

JO - Chem

JF - Chem

IS - 2

ER -

Using small building blocks to assemble ultra-complex, multifaceted metal-organic frameworks with zeolitic, mesoporous subnetwork

Abstract

Keywords

ASJC Scopus subject areas

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