Visible-light-promoted C-C bond cleavage: Photocatalytic generation of iminium ions and amino radicals

Shunyou Cai; Xinyang Zhao; Xinbo Wang; Qisong Liu; Zigang Li; David Zhigang Wang

doi:10.1002/anie.201202880

Visible-light-promoted C-C bond cleavage: Photocatalytic generation of iminium ions and amino radicals

Shunyou Cai, Xinyang Zhao, Xinbo Wang, Qisong Liu, Zigang Li^*, David Zhigang Wang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

133 Scopus citations

Abstract

Photoscissors: Structurally variable and synthetically robust iminium ions and amino radicals species could be simultaneously generated by visible-light-promoted photoredox cleavage of the C-C bonds in simple vicinal diamine precursors under very mild reaction conditions.

Original language	English (US)
Pages (from-to)	8050-8053
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	32
DOIs	https://doi.org/10.1002/anie.201202880
State	Published - Aug 6 2012
Externally published	Yes

Keywords

C-C activation
amines
photochemistry
radicals
ruthenium

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.201202880

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title = "Visible-light-promoted C-C bond cleavage: Photocatalytic generation of iminium ions and amino radicals",

abstract = "Photoscissors: Structurally variable and synthetically robust iminium ions and amino radicals species could be simultaneously generated by visible-light-promoted photoredox cleavage of the C-C bonds in simple vicinal diamine precursors under very mild reaction conditions.",

keywords = "C-C activation, amines, photochemistry, radicals, ruthenium",

author = "Shunyou Cai and Xinyang Zhao and Xinbo Wang and Qisong Liu and Zigang Li and Wang, {David Zhigang}",

year = "2012",

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T2 - Photocatalytic generation of iminium ions and amino radicals

AU - Cai, Shunyou

AU - Zhao, Xinyang

AU - Wang, Xinbo

AU - Liu, Qisong

AU - Li, Zigang

AU - Wang, David Zhigang

PY - 2012/8/6

Y1 - 2012/8/6

N2 - Photoscissors: Structurally variable and synthetically robust iminium ions and amino radicals species could be simultaneously generated by visible-light-promoted photoredox cleavage of the C-C bonds in simple vicinal diamine precursors under very mild reaction conditions.

AB - Photoscissors: Structurally variable and synthetically robust iminium ions and amino radicals species could be simultaneously generated by visible-light-promoted photoredox cleavage of the C-C bonds in simple vicinal diamine precursors under very mild reaction conditions.

KW - C-C activation

KW - amines

KW - photochemistry

KW - radicals

KW - ruthenium

UR - http://www.scopus.com/inward/record.url?scp=84864774783&partnerID=8YFLogxK

U2 - 10.1002/anie.201202880

DO - 10.1002/anie.201202880

M3 - Article

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AN - SCOPUS:84864774783

SN - 1433-7851

VL - 51

SP - 8050

EP - 8053

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 32

ER -

Visible-light-promoted C-C bond cleavage: Photocatalytic generation of iminium ions and amino radicals

Abstract

Keywords

ASJC Scopus subject areas

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