Water-soluble diphosphadiazacyclooctanes as ligands for aqueous organometallic catalysis

Jérôme Boulanger; Hervé Bricout; Sébastien Tilloy; Aziz Fihri; Christophe Len; Frédéric Hapiot; Éric Monflier

doi:10.1016/j.catcom.2012.09.019

Water-soluble diphosphadiazacyclooctanes as ligands for aqueous organometallic catalysis

Jérôme Boulanger, Hervé Bricout, Sébastien Tilloy, Aziz Fihri, Christophe Len, Frédéric Hapiot, Éric Monflier

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Two new water-soluble diphosphacyclooctanes been synthesized and characterized by NMR and surface tension measurements. Both phosphanes proved to coordinate rhodium in a very selective way as well-defined bidentates were obtained. When used in Rh-catalyzed hydroformylation of terminal alkenes, both ligands positively impacted the reaction chemoselectivity. © 2012 Elsevier B.V.

Original language	English (US)
Pages (from-to)	77-81
Number of pages	5
Journal	Catalysis Communications
Volume	29
DOIs	https://doi.org/10.1016/j.catcom.2012.09.019
State	Published - Dec 2012

ASJC Scopus subject areas

General Chemistry
Catalysis
Process Chemistry and Technology

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10.1016/j.catcom.2012.09.019

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title = "Water-soluble diphosphadiazacyclooctanes as ligands for aqueous organometallic catalysis",

abstract = "Two new water-soluble diphosphacyclooctanes been synthesized and characterized by NMR and surface tension measurements. Both phosphanes proved to coordinate rhodium in a very selective way as well-defined bidentates were obtained. When used in Rh-catalyzed hydroformylation of terminal alkenes, both ligands positively impacted the reaction chemoselectivity. {\textcopyright} 2012 Elsevier B.V.",

author = "J{\'e}r{\^o}me Boulanger and Herv{\'e} Bricout and S{\'e}bastien Tilloy and Aziz Fihri and Christophe Len and Fr{\'e}d{\'e}ric Hapiot and {\'E}ric Monflier",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by the Centre National de la Recherche Scientifique (CNRS).",

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doi = "10.1016/j.catcom.2012.09.019",

language = "English (US)",

volume = "29",

pages = "77--81",

journal = "Catalysis Communications",

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T1 - Water-soluble diphosphadiazacyclooctanes as ligands for aqueous organometallic catalysis

AU - Boulanger, Jérôme

AU - Bricout, Hervé

AU - Tilloy, Sébastien

AU - Fihri, Aziz

AU - Len, Christophe

AU - Hapiot, Frédéric

AU - Monflier, Éric

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by the Centre National de la Recherche Scientifique (CNRS).

PY - 2012/12

Y1 - 2012/12

N2 - Two new water-soluble diphosphacyclooctanes been synthesized and characterized by NMR and surface tension measurements. Both phosphanes proved to coordinate rhodium in a very selective way as well-defined bidentates were obtained. When used in Rh-catalyzed hydroformylation of terminal alkenes, both ligands positively impacted the reaction chemoselectivity. © 2012 Elsevier B.V.

AB - Two new water-soluble diphosphacyclooctanes been synthesized and characterized by NMR and surface tension measurements. Both phosphanes proved to coordinate rhodium in a very selective way as well-defined bidentates were obtained. When used in Rh-catalyzed hydroformylation of terminal alkenes, both ligands positively impacted the reaction chemoselectivity. © 2012 Elsevier B.V.

UR - http://hdl.handle.net/10754/562435

UR - https://linkinghub.elsevier.com/retrieve/pii/S1566736712003585

UR - http://www.scopus.com/inward/record.url?scp=84867480725&partnerID=8YFLogxK

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DO - 10.1016/j.catcom.2012.09.019

M3 - Article

SN - 1566-7367

VL - 29

SP - 77

EP - 81

JO - Catalysis Communications

JF - Catalysis Communications

ER -

Water-soluble diphosphadiazacyclooctanes as ligands for aqueous organometallic catalysis

Abstract

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