Well-defined azazirconacyclopropane complexes supported on silica structurally determined by 2D NMR comparative elucidation

Mohamad El Eter; Bilel Hamzaoui; Edy Abou-Hamad; Jeremie Pelletier; Jean-Marie Basset

doi:10.1039/c3cc40385h

Well-defined azazirconacyclopropane complexes supported on silica structurally determined by 2D NMR comparative elucidation

Mohamad El Eter, Bilel Hamzaoui, Edy Abou-Hamad, Jeremie Pelletier, Jean-Marie Basset

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Grafting of Zr(NMe2)4 on mesoporous silica SBA-15 afforded selectively well-defined surface species SiOZr(NMe2) (η2NMeCH2). 2D solid-state NMR (1H- 13C HETCOR, Multiple Quantum) experiments have shown a unique structural rearrangement occurring on the immobilised zirconium bis methylamido ligand. © The Royal Society of Chemistry 2013.

Original language	English (US)
Pages (from-to)	4616
Journal	Chemical Communications
Volume	49
Issue number	41
DOIs	https://doi.org/10.1039/c3cc40385h
State	Published - 2013

ASJC Scopus subject areas

Materials Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Ceramics and Composites
General Chemistry
Catalysis
Electronic, Optical and Magnetic Materials

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title = "Well-defined azazirconacyclopropane complexes supported on silica structurally determined by 2D NMR comparative elucidation",

abstract = "Grafting of Zr(NMe2)4 on mesoporous silica SBA-15 afforded selectively well-defined surface species SiOZr(NMe2) (η2NMeCH2). 2D solid-state NMR (1H- 13C HETCOR, Multiple Quantum) experiments have shown a unique structural rearrangement occurring on the immobilised zirconium bis methylamido ligand. {\textcopyright} The Royal Society of Chemistry 2013.",

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T1 - Well-defined azazirconacyclopropane complexes supported on silica structurally determined by 2D NMR comparative elucidation

AU - El Eter, Mohamad

AU - Hamzaoui, Bilel

AU - Abou-Hamad, Edy

AU - Pelletier, Jeremie

AU - Basset, Jean-Marie

N1 - KAUST Repository Item: Exported on 2020-10-01

PY - 2013

Y1 - 2013

N2 - Grafting of Zr(NMe2)4 on mesoporous silica SBA-15 afforded selectively well-defined surface species SiOZr(NMe2) (η2NMeCH2). 2D solid-state NMR (1H- 13C HETCOR, Multiple Quantum) experiments have shown a unique structural rearrangement occurring on the immobilised zirconium bis methylamido ligand. © The Royal Society of Chemistry 2013.

AB - Grafting of Zr(NMe2)4 on mesoporous silica SBA-15 afforded selectively well-defined surface species SiOZr(NMe2) (η2NMeCH2). 2D solid-state NMR (1H- 13C HETCOR, Multiple Quantum) experiments have shown a unique structural rearrangement occurring on the immobilised zirconium bis methylamido ligand. © The Royal Society of Chemistry 2013.

UR - http://hdl.handle.net/10754/562557

UR - http://xlink.rsc.org/?DOI=c3cc40385h

UR - http://www.scopus.com/inward/record.url?scp=84876910449&partnerID=8YFLogxK

U2 - 10.1039/c3cc40385h

DO - 10.1039/c3cc40385h

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SN - 1359-7345

VL - 49

SP - 4616

JO - Chemical Communications

JF - Chemical Communications

IS - 41

ER -

Well-defined azazirconacyclopropane complexes supported on silica structurally determined by 2D NMR comparative elucidation

Abstract

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