TY - JOUR
T1 - Well-Defined Copper(I) Fluoroalkoxide Complexes for Trifluoroethoxylation of Aryl and Heteroaryl Bromides
AU - Huang, Ronglu
AU - Huang, Yangjie
AU - Lin, Xiaoxi
AU - Rong, Mingguang
AU - Weng, Zhiqiang
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: Financial support from the National Natural Science Foundation of China (NSFC) (grant number 21372044), the Research Fund for the Doctoral Program of Higher Education of China (grant number 20123514110003), and Fuzhou University (grant numbers 022318, 022494) is gratefully acknowledged. We thank Prof. Kuo-Wei Huang (KAUST) for insightful discussions.
This publication acknowledges KAUST support, but has no KAUST affiliated authors.
PY - 2015/3/17
Y1 - 2015/3/17
N2 - © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Copper(I) fluoroalkoxide complexes bearing dinitrogen ligands were synthesized and the structure and reactivity of the complexes toward trifluoroethoxylation, pentafluoropropoxylation, and tetrafluoropropoxylation of aryl and heteroaryl bromides were investigated. Efficiency drive: A series of copper(I) fluoroalkoxide complexes bearing N,N ligands have been prepared and structurally characterized. These well-defined complexes serve as efficient reagents for the fluoroalkoxylation of aryl and heteroaryl bromides to produce a wide range of trifluoroethyl, pentafluoropropyl, and tetrafluoropropyl (hetero)aryl ethers in good to excellent yields.
AB - © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Copper(I) fluoroalkoxide complexes bearing dinitrogen ligands were synthesized and the structure and reactivity of the complexes toward trifluoroethoxylation, pentafluoropropoxylation, and tetrafluoropropoxylation of aryl and heteroaryl bromides were investigated. Efficiency drive: A series of copper(I) fluoroalkoxide complexes bearing N,N ligands have been prepared and structurally characterized. These well-defined complexes serve as efficient reagents for the fluoroalkoxylation of aryl and heteroaryl bromides to produce a wide range of trifluoroethyl, pentafluoropropyl, and tetrafluoropropyl (hetero)aryl ethers in good to excellent yields.
UR - http://hdl.handle.net/10754/600190
UR - http://doi.wiley.com/10.1002/anie.201501257
UR - http://www.scopus.com/inward/record.url?scp=84929493286&partnerID=8YFLogxK
U2 - 10.1002/anie.201501257
DO - 10.1002/anie.201501257
M3 - Article
C2 - 25783796
SN - 1433-7851
VL - 54
SP - 5736
EP - 5739
JO - Angewandte Chemie International Edition
JF - Angewandte Chemie International Edition
IS - 19
ER -