TY - JOUR
T1 - Well-defined single-site monohydride silica-supported zirconium from azazirconacyclopropane
AU - Hamzaoui, Bilel
AU - El Eter, Mohamad
AU - Abou-Hamad, Edy
AU - Chen, Yin
AU - Pelletier, Jeremie
AU - Basset, Jean-Marie
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: The authors wish to thank the King Abdullah University of Science and Technology for continuous support.
PY - 2015/1/13
Y1 - 2015/1/13
N2 - The silica-supported azazirconacyclopropane ≡SiOZr(HNMe2)(η2-NMeCH2)(NMe2) (1) leads exclusively under hydrogenolysis conditions (H2, 150°C) to the single-site monopodal monohydride silica-supported zirconium species ≡SiOZr(HNMe2)(NMe2)2H (2). Reactivity studies by contacting compound 2 with ethylene, hydrogen/ethylene, propene, or hydrogen/propene, at a temperature of 200°C revealed alkene hydrogenation.
AB - The silica-supported azazirconacyclopropane ≡SiOZr(HNMe2)(η2-NMeCH2)(NMe2) (1) leads exclusively under hydrogenolysis conditions (H2, 150°C) to the single-site monopodal monohydride silica-supported zirconium species ≡SiOZr(HNMe2)(NMe2)2H (2). Reactivity studies by contacting compound 2 with ethylene, hydrogen/ethylene, propene, or hydrogen/propene, at a temperature of 200°C revealed alkene hydrogenation.
UR - http://hdl.handle.net/10754/564007
UR - http://doi.wiley.com/10.1002/chem.201405788
UR - http://www.scopus.com/inward/record.url?scp=84922439716&partnerID=8YFLogxK
U2 - 10.1002/chem.201405788
DO - 10.1002/chem.201405788
M3 - Article
C2 - 25585538
SN - 0947-6539
VL - 21
SP - 4294
EP - 4299
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 11
ER -