Abstract
ZnAlF5·[TAZ], the first aluminium fluorinated metal-organic framework with cationic {Zn(1,2,4 triazole)}2+ linkers has been synthesized. The structure is accurately determined by coupling direct space methods on laboratory powder X-ray diffraction data with solid-state nuclear magnetic resonance experiments and ab initio calculations, and is found to be analogous to that of MIL-53(Al).
Original language | English (US) |
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Pages (from-to) | 3949-3951 |
Number of pages | 3 |
Journal | Journal of Materials Chemistry |
Volume | 21 |
Issue number | 11 |
DOIs | |
State | Published - 2011 |
Externally published | Yes |
ASJC Scopus subject areas
- General Chemistry
- Materials Chemistry